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To roast a pepper – the sweet peppers like green bell peppers, yellow and orange bell peppers and especially red bell peppers – is to change not only its texture but its flavor. A raw pepper is wet and crunchy, a roasted pepper is slippery and smoky.
This same technique works not only with sweet peppers but also with hot chile peppers with a little or a lot of heat. My favorite pepper for roasting is a poblano chile (as picture) but I've also roasted jalapeños and other chiles.
Mostly it's a hands-off operation, just throw the pepper on the fire, then carry on in the kitchen – no wandering off, now, it's not that hands-off! – keeping an eye on the roasting process, turning as needed.
The technique is best for roasting one or two peppers, for a whole trayful, you'll want to follow this technique that works in both gas and electric ovens, How to Roast Peppers in the Oven.
And I should add one more thing, and that's that when I was cooking on a typical kitchen stove, I didn't have much luck roasting peppers this way, it seemed to just take too long. So it's possible that this technique works only with high-BTU commercial stovetops like Viking and Wolf. Or maybe you have more patience than I!
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